 |
Journal articles
Modified Julia Olefination on Anhydrides: Extension and Limitations. Application to the Synthesis of Maculalactone B
Abstract : The preparation of exo-enol esters from cyclic anhydrides is reported using a modified Julia olefination. The reaction is highly stereoselective. The Smiles rearrangement can be performed in a one-pot process, giving a straightforward access to exo-enol lactones. Furthermore, the reaction was extended to semistabilized sulfones, and this methodology was applied to the synthesis of maculalactone B.
https://hal-udl.archives-ouvertes.fr/hal-02122513
Contributor : Umr5246 Icbms <>
Submitted on : Tuesday, May 7, 2019 - 1:59:14 PM
Last modification on : Friday, June 25, 2021 - 7:38:02 PM
Contributor : Umr5246 Icbms <>
Submitted on : Tuesday, May 7, 2019 - 1:59:14 PM
Last modification on : Friday, June 25, 2021 - 7:38:02 PM