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Journal articles
Solvent issues in the Baylis-Hillman reaction of 5-hydroxymethyl furfural (HMF) and 5-glucosyloxymethyl furfural (GMF). Towards no-solvent conditions
Abstract : The possibility to apply solventless conditions for the Baylis-Hillman reaction of 5-hydroxymethyl furfural (HMF) and its glucosylated analogue, glucosyloxymethyl furfural (GMF) has been investigated. This study shows that highly functionalized adducts can be obtained in fair to good yields, under the conditions combining the renewability of the substrates, the straightforwardness of the strategy, and the lowered cost and toxicity of the solvent conditions. The issue of the polarity of the furanic substrate is addressed by comparing HMF with furfural and GMF.
Cited literature [65 references]
https://hal-udl.archives-ouvertes.fr/hal-02193113
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Submitted on : Wednesday, July 15, 2020 - 4:11:12 PM
Last modification on : Tuesday, September 27, 2022 - 4:23:58 AM
Long-term archiving on: : Monday, November 30, 2020 - 2:30:09 PM
Contributor : UMR5246 ICBMS Connect in order to contact the contributor
Submitted on : Wednesday, July 15, 2020 - 4:11:12 PM
Last modification on : Tuesday, September 27, 2022 - 4:23:58 AM
Long-term archiving on: : Monday, November 30, 2020 - 2:30:09 PM
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