2,3,5-Tri-O-benzyl-D-xylofuranose

Baptiste Taffoureau (1) , Isabelle Gillaizeau (1) , Pascal Retailleau (2) , Cyril Nicolas (1)

1 ICOA - Institut de Chimie Organique et Analytique
2 ICSN - Institut de Chimie des Substances Naturelles

The synthesis and crystallization of 2,3,5-tri-O-benzyl-D-xylofuranose permitted us to isolate the alpha anomer with a small contamination of the beta form (ca 10%), whose first crystallographic structure obtained in the P2$_1$2$_1$2$_1$ space group was determined at 100 K up to a resolution of sin θmax/λ = 0.71 Å$^{−1}$ and refined to an R1 value of 0.0171 with a Hirshfeld atom refinement (HAR) approach

Mots clés: Tri-O-benzyl-D-xylofuranose 2; tri-O-benzyl-D-xylofuranose; synthesis; Hirshfeld atom refinement of X-ray structure; 3-D Hirshfeld surface; crystal packing

Domaines: Chimie

Baptiste Taffoureau, Isabelle Gillaizeau, Pascal Retailleau, Cyril Nicolas. 2,3,5-Tri-O-benzyl-D-xylofuranose. Molbank, 2022, 2022, pp.M1382. ⟨10.3390/m1382⟩. ⟨hal-03798544⟩