Pd@[nBu4][Br] as a simple catalytic system for N-alkylation reactions with alcohols

Bastien Cacciuttolo (1) , Oana Pascu (2) , Cyril Aymonier (2) , Mathieu Pucheault (1)

1 ISM - Institut des Sciences Moléculaires
2 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux

Palladium nanoparticles, simply and briefly generated in commercial and cheap onium salts using supercritical carbon dioxide, have been found to be an effective catalytic system for additive free N-alkylation reaction using alcohols via cascade oxidation/condensation/reduction steps.

Mots clés: N-alkylation; nanoparticle; onium salt; N-alkylation; onium salt N-alkylation

Domaines: Matériaux

Bastien Cacciuttolo, Oana Pascu, Cyril Aymonier, Mathieu Pucheault. Pd@[nBu4][Br] as a simple catalytic system for N-alkylation reactions with alcohols. Molecules, 2016, 21 (8), 1042 (13 p.). ⟨10.3390/molecules21081042⟩. ⟨hal-01370330⟩